The Azzurri will travel to Verona for their first match of the new season, as they kick off their campaign on 15 August.
Here are the details of their first five games of the 2022/23 season:
Matchday 1: Verona v Napoli, 15 August at 18:30 CEST
Matchday 2: Napoli v Monza, 21 August at 18:30 CEST
Matchday 3: Fiorentina v Napoli, 28 August at 20:45 CEST
Matchday 4: Napoli v Lecce, 31 August at 20:45 CEST
Matchday 5: Lazio v Napoli, 3 September at 20:45 CEST