Napoli will travel to Hellas Verona on the opening day of the new season then host Bologna at the Stadio Maradona for their first home game in Week 2.
The full fixture list for the 2024/25 Serie A season was released on Thursday.
The Verona game will be played on the weekend of 17/18 August with the Bologna fixture a week later. The dates and kick-off times will be confirmed in the coming days.
Parma will be the visitors in Week 3 (31 August/1 September) before the first international break.
The first big match of the season will see the Azzurri visit Juventus in Week 5 (21/22 September) and Antonio Conte's side will also face both of the Milan teams away in the first half of the campaign – AC Milan in Week 10 and Inter in Week 12.
The only midweek round is scheduled for 29-31 October.
There will be four weekends with no Serie A action due to international matches: 7/8 September, 12/13 October, 16/17 November and 22/23 March.
The final round of games will take place on 24/25 May.